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Organic and Organometallic Chemistry

The Organic and Organometallic division at UC Merced has a strong background in physical organic chemistry, materials chemistry, and synthetic organometallic chemistry and catalysis that empowers the discovery and understanding of chemical reactions and the synthesis of new functional molecules combining organic and inorganic techniques.

Ph.D. students choose from graduate classes in Advanced Organic Synthesis, Organic and Organometallic Reaction Mechanisms, Physical Organic Chemistry, Advanced Inorganic Chemistry, Organometallic and Coordination Chemistry.Student in lab

Ryan Baxter’s group is developing new catalytic reactions starting from inexpensive feedstock chemicals. At the core of their research is the use of kinetic analysis to guide the development of metal-catalyzed single-electron transformation.

Rebeca Arevalo’s group focuses on developing new sustainable catalytic processes for the functionalization of inert bonds by rationally-guided catalyst design. The discovery of C-H functionalization processes employing Earth-abundant transition-metal complexes and the investigation of their mechanisms are among their main interests.

Yue (Jessica) Wang’s group synthesizes organic metal and semiconductor systems that possess properties typically not associated with electronic materials, such as elasticity, self-healing capability, and biodegradability, while keeping environmental sustainability in mind by practicing green chemistry for synthesis and additive manufacturing for processing. 

 

Representative Publications

Rebeca Arevalo, Tyler P. Pabst, Paul J. Chirik, “C(sp2)–H Borylation of Heterocycles by Well-Defined Bis(silylene)pyridine Cobalt(III) Precatalysts: Pincer Modification, C(sp2)–H Activation, and Catalytically Relevant IntermediatesOrganometallics,  39, 14, 2763–2773 (2020)

Jordan D. Galloway, Duy N. Mai, Ryan Baxter, “Radical Benzylation of Quinones via C–H Abstraction.” J. Org. Chem., 84, 18, 12131–12137 (2019)

Robert Jordan, Yue Wang,  "3D printing of conjugated polymers,” Polym. Sci., Part B: Polym. Phys., 57, 23, 1592-1605. (2019)

Rebeca Arevalo, Paul J. Chirik, “Enabling Two-Electron Pathways with Iron and Cobalt: From Ligand Design to Catalytic ApplicationsJ. Am. Chem. Soc.,  141, 23, 9106–9123 (2019)

Yue Wang, Guihua Yu, "Conjugated polymers: From synthesis, transport properties, to device applications,” J. Polym. Sci., Part B: Polym. Phys., 57, 23, 2557-1558. (2019)

Hua, A. M.; Bidwell, S. L.; Baker, S. I.; Hratchian, H. P.; Baxter, R. D. "Experimental and Theoretical Evidence for Nitrogen–Fluorine Halogen Bonding in Silver-Initiated Radical Fluorinations." ACS Catalysis, 9, 3322–3326. (2019)

Akil Hamsath, Jordan D. Galloway, Ryan D. Baxter, “Quinone C–H Alkylations via Oxidative Radical Processes.” Synthesis, 50, 2915–2923 (2018)

Galloway, J. D.; Mai, D. N.; Baxter, R. D  "Silver-Catalyzed Minisci Reactions Using Selectfluor as a Mild Oxidant."Org. Lett, 19, 5772–5775. (2017)